Trimetallic Spinel NiCo <sub> 2− <i>x</i> </sub> Fe <sub> <i>x</i> </sub> O <sub>4</sub> Nanoboxes for Highly Efficient Electrocatalytic Oxygen Evolution
نویسندگان
چکیده
The development of efficient and low-cost electrocatalysts toward the oxygen evolution reaction (OER) is critical for improving efficiency several electrochemical energy conversion storage devices. Here, we report an elaborate design synthesis porous Co-based trimetallic spinel oxide nanoboxes (NiCo2−xFexO4 NBs) by a novel metal-organic framework engaged strategy, which involves chemical etching, cation exchange, subsequent thermal oxidation processes. Owing to structural compositional advantages, optimized NiCo2−xFexO4 NBs (x about 0.117) deliver superior electrocatalytic performance OER with overpotential 274 mV at 10 mA cm−2, small Tafel slope 42 dec−1, good stability in alkaline electrolyte, much better than that bi/monometallic oxides even commercial RuO2.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202103058